Process and exhaust treatment system for treating an exhaust stream

专利摘要:
The present invention provides an exhaust gas treatment system and method for treating exhaust gas flow from an internal combustion engine. This exhaust stream includes nitrogen oxides NOX, in which nitrogen monoxide NO and nitrogen dioxide NO2 are included. The exhaust gas flow passes through a exhaust gas treatment system connected to the internal combustion engine. In the exhaust gas treatment system, a first oxidation of compounds comprising one or more of the nitrogen, carbon and hydrogen exhaust gas streams of a first oxidation catalyst is performed. A value (NO¿¿ / NO & ¿) m¶ is further determined for a ratio between the first quantity of nitrogen dioxide NO¿¿ and a first quantity of nitrogen oxides NO & ¿which leave the first oxidation catalyst. An active control of at least one parameter related to the internal combustion engine is performed based on the determined value (NO¿¿ / NO & ¿) m¶, whereby the condition is affected. A first additive is fed to the exhaust gas stream, after which a first reduction of the first amount of nitrogen oxides NO & ¿is carried out by a catalytic reaction in a catalytic filter, where the filter consists of a particulate filter with at least partial catalytic coating with reduction properties. The catalytic filter is arranged to pre-capture and oxidize soot particles, and to carry out the first reduction of the first amount of nitrogen oxides NO & ¿by using the first additive. Fig. 2
公开号:SE1551107A1
申请号:SE1551107
申请日:2015-08-27
公开日:2017-02-28
发明作者:Nilsson Magnus；Birgersson Henrik
申请人:Scania Cv Ab；
IPC主号:

专利说明:

TECHNICAL FIELD The present invention relates to a method for treating an exhaust stream according to the preamble of claim 1. The present invention also relates to an exhaust treatment system arranged for pre-treatment of an exhaust gas and an exhaust gas treatment system. the invention.
Background The following background description is a description of the background of the present invention, and thus does not necessarily constitute prior art.
Due to increased government interests regarding pollution and air quality, especially in urban areas, emission standards and emission rules for internal combustion engines have been developed in many jurisdictions.
Such emission or emission standards often constitute requirement sets which define acceptable limits pre-exhaust emissions from internal combustion engines in, for example, vehicles. For example, nitrogen emission levels are often regulated NOW hydrocarbons Cgg, carbon monoxide CO and particulate matter PM particles for most types of vehicles in these standards. Vehicles equipped with internal combustion engines typically give rise to these emissions to varying degrees. This document describes the invention mainly for its application in vehicles. However, the invention can be used in essentially all applications where internal combustion engines are used, for example in vehicles, such as aircraft or aircraft / helicopters, whereby rules and / or standards for these applications limit the emissions from the internal combustion engines. In an effort to meet such emission standards, the exhaust gases caused by the combustion engine combustion are treated (purified).
A common method of treating exhaust gases from a single-combustion engine consists of a so-called catalytic purification process, which is why vehicles equipped with a single-combustion engine usually comprise at least one catalyst. There are different types of catalysts, where the different types can be suitable depending on, for example, which combustion concepts, combustion strategies and / or industry types are used in the vehicles and / or which types of compounds in the exhaust stream are to be purified. At least nitrous gases (nitrogen monoxide, nitrogen dioxide), in this document called nitrogen oxides NOX, vehicles often comprise a catalyst where an additive is fed to the combustion engine of the exhaust gas combustion gas exhaust gas to bring about a reduction of nitrogen oxides NOX mainly to nitrogen gas and water vapor.
A common type of catalyst in this type of reduction, especially for heavy vehicles, is SCR (SelectiveCatalytic Reduction) catalysts. SCR catalysts usually use ammonia NH3, or a compound from which ammonia can be generated / formed, as an additive which is used for the reduction of the nitrogen oxides NOX in the exhaust gases. The additive is injected into the exhaust stream resulting from the internal combustion engine upstream of the catalyst. The additive fed to the catalyst is adsorbed (stored) in the catalyst, in the form of ammonia NH3, whereby a redox reaction can take place between nitrogen oxides NOX in the exhaust gases and ammonia NH3 available through the additive. 10 A modern internal combustion engine is a system where there is sole effect and mutual influence between engine and exhaust gas treatment. In particular, there is a link between the ability to reduce nitrogen oxides NOX in the exhaust gas treatment system and the fuel efficiency of the internal combustion engine. Namely, the pre-combustion engine has a connection between engine fuel efficiency / efficiency and its produced nitrogen oxides NOX. This connection indicates that for a given system there is a positive connection between produced nitrogen oxides NOX and the industry efficiency, ie that an engine that is allowed to emit more nitrogen oxides NOX can be made to consume less fuel, which can give a higher combustion efficiency. Correspondingly, there is often a negative connection between a produced particulate mass PM and the fuel efficiency, ie an increased emission of particulate matter PM from the engine links to an increase in fuel consumption.
These relationships form the background to the widespread use of exhaust gas treatment systems including an SCR catalyst, which is intended to optimize the industry and particulate matter against a relatively larger amount of produced nitrogen oxides NOX. A reduction of these nitrogen oxides NOX is then performed in the exhaust gas treatment system, which may thus include an SCR catalyst. Through an integrated approach to the design of the engine and exhaust gas treatment system, where engine and exhaust gas treatment complement each other, a high fuel efficiency can therefore be achieved together with low emissions of both PM and nitrogen oxides NOX.
Brief description of the invention To a certain extent, the performance of exhaust gas treatment systems can be increased by increasing the substrate volumes included in the exhaust gas treatment systems, which in particular reduces the losses due to uneven distribution of the exhaust flow through the substrates. At the same time a larger substrate volume gives a greater partial pressure. can counteract gains in fuel efficiency from the higher conversion rate. Large substrate volumes also entailed an increased cost. It is thus important to be able to utilize the exhaust gas treatment systems optimally, for example by avoiding oversizing and / or by limiting the spread of the exhaust gas treatment systems in size and / or manufacturing cost.
The function and efficiency of catalysts in general, and of catalysts with reduction properties in particular, are for example dependent on a ratio between nitrogen dioxide and nitrogen oxides, i.e. the NO2 / NOX content, in the exhaust gases. However, the NO2 / NOX content depends on a number of factors, e.g. for example, the NO2 / NOX content in the exhaust gases may depend on the torque required by a driver and / or a cruise control, on the head section on which the vehicle is located and / or the driver's cross style. An example of a critical operating case is load load when the exhaust temperature is relatively low. In this case of operation, there is a risk that the value of the ratio N02 / NOX will be too low.
For certain conditions for catalyst temperature and flow, ie for a certain residence time in the catalyst ("SpaceVelocity"), there is a risk that a non-advantageous proportion of nitrogen dioxide NO2 over nitrogen oxides NOX is obtained. In particular, there is a risk that the NO2 / NOX ratio exceeds 50%, which can be a real problem for exhaust gas purification.
An optimization of the NO2 / NOX ratio for any of the above-mentioned critical operating cases risks giving an excessively high proportion of nitrogen dioxide NO2 in other operating cases. This higher proportion of 10 nitrogen dioxide NO2 results in a larger volume language in the pre-gas light emitter with reduction properties and / or in a limitation of the amount of nitrogen oxides emitted from the engine and thus in a poorer fuel efficiency for the vehicle.
In addition, there is a risk that the higher proportion of nitrogen dioxide N02 also results in emissions of nitrous oxide N20.
These risks for a non-beneficial amount of nitrogen dioxide N02 arise also exist due to aging of the system. änvendäs for ätt tä hojd for, och kunnä kompenserä for, åldrändet.
There are also known goose treatment systems which comprise a ketalytic particle filter SCRF, such as for example WO20l40443l8. A kätälytic particle filter is a filter which comprises a kätälytic coating which the properties of the coating can be used for the reduction of nitrogen oxides N0X. However, these known gas treatment systems often have problems relaying to a substandard sotoxidation in the SCRF filter. These problems are due at least in part to the reactions included in the reduction of nitrogen oxides N0X are faster than the reactions included in the sotoxidation.
Thus, there is a need for an optimization of the function of the goose treatment system.
It is therefore an object of the present invention to provide a prior art and a system which is known to have a high performance and good function under different conditions. This object is achieved by the above-mentioned method according to the characterizing part of claim 1. The object is achieved by the above-mentioned exhaust gas treatment system according to the characterizing part of claim 30, and by the above-mentioned computer program and computer program product.
The present invention provides a treatment of single exhaust stream resulting from a combustion in a single combustion engine. This exhaust stream comprises nitrogen oxides NOWi which include at least nitrogen monoxide NO and nitrogen dioxide NO2. The exhaust stream passes through an exhaust gas treatment system connected to the internal combustion engine.
In the exhaust gas treatment system, a first oxidation of compounds comprising one or more of the nitrogen, carbon and hydrogen in the exhaust stream is performed. This oxidation is carried out by a first oxidation catalyst arranged in the exhaust gas treatment system.
According to the present invention, a value (NO¿¿ / NO & ¿) m% is determined for a ratio between a first amount of nitrogen dioxide NO¿¿ which leaves the first oxidation catalyst and a first amount of nitrogen oxides NO & ¿which leaves the first oxidation catalyst.
Based on this determined value (NO¿¿ / NO & ¿) m¶ the ratio is then performed an active control of at least one parameter related to the internal combustion engine, this active control affecting the ratio.
A first supply of a first additive into the exhaust gas stream is carried out by using a suburban metering device arranged downstream of the first oxidation catalyst.
This first additive is then used in a first reduction of the first amount of nitrogen oxides NO & ¿by a 10 catalytic reaction in a catalytic filter arranged downstream of the first dosing device. This catalytic filter consists of a particle filter with an at least partial viscous catalytic coating with reduction properties. The catalytic filter is thus arranged for capturing and oxidizing soot particles, and for carrying out the first reduction of the first amount of nitrogen oxides NO & ¿.
An active control of at least one parameter related combustion engine is thus performed according to the present invention based on the determined value (NO¿¿ / NO & ¿) m¶ ratio. This active control is performed so that the ratio, and thus also a real value NO¿¿ / NO & ¿ratio, changes compared to the determined value (NO2 * 1 / N @ X * 1) it.
This active control of at least one parameter related to the internal combustion engine provided by the present invention can provide an improved sotoxidation in the catalytic filter. More specifically, an improved passive nitrogen dioxide based sotoxidation can be achieved by this activation control of the engine, since the control can be performed so that part of the nitrogen dioxide NO¿¿ which reaches the catalytic filter can be used to oxidize soot particles in the catalytic filter, instead of being consumed by the reduction. the coating in the filter.
In other words, the active control of at least one engine-related parameter can be performed in such a way that the first reduction of nitrogen oxides NO & ¿in that catalytic filter is limited so that not all nitrogen dioxide NO¿¿ in the exhaust gas stream is consumed in the first reduction, the rest of the nitrogen dioxide not being consumed can be used in sotoxidation. Oxidation catalysts have several properties that are important for the exhaust gas treatment system. One of these properties is that the oxidation catalyst oxidizes nitrogen oxide N0 present in the exhaust stream to nitrogen dioxide NO2. The supply of nitrogen dioxide NO2 is important partly for the nitrogen dioxide-based deoxidation in the filter and partly for the reduction of nitrogen oxides NOX. The exhaust gas treatment system of the present invention can therefore provide good sotoxidation in the catalytic filter due to the availability of nitrogen dioxide NO2¿ after the first oxidation catalyst.
The active control of the internal combustion engine according to the present invention means that the proportion of the total conversion of nitrogen oxides N0X that takes place via a fast reaction wave, i.e. via fast SCR ("solid SCR"), the reduction takes place via reaction waves over both nitrogen oxide N0 and nitrogen dioxide N02, can be increased for some operational cases. This reduces the volume requirements for the reducing system, and thus for the entire exhaust gas treatment system. Reaction utilizes in fast SCR equal parts nitrogen monoxide N0 and nitrogen dioxide N02, which makes it important to be able to control the molar ratio N02 / N0X, towards an appropriate value, for example a value close to 0.5 (50%).
The load on the catalytic filter and / or the reduction catalyst increases for certain embodiments of the elevated level of nitrogen oxides NOX. However, the filters and / or catalysts which carry out the reduction of nitrogen oxides NOX will have good conditions to withstand this load, since the increase is primarily relevant at a harmless exhaust gas temperature of around 260-340 ° C, where the catalysts have rather good performance.
By a suitably selected active control of the internal combustion engine according to the present invention, the requirements for the volume of the reducing system can also be reduced as the degree of utilization is improved.
Utilization of the present invention may also result in a reduced consumption of additives. In addition, NO2 emissions from the vehicle can be reduced.
The exhaust gas treatment system also becomes easier to regulate / control if the present invention is used, which means that a more precise control of the supply of additives can be performed.
In addition, the active control of the internal combustion engine according to the present invention, which has been made primarily to optimize NOx conversion, also provides a reduced fuel consumption for the vehicle as a positive side effect.
The present invention can also be used to advantage in hybrid vehicles. The hybrid system can then give the internal combustion engine increased flexibility for controlling the N02 / N0X ratio.
By utilizing the present invention, a better fuel optimization can be obtained for the vehicle, since it thereby has the potential to control the engine more fuel efficiently, for example by increasing a first amount of nitrogen oxides NO22 which reaches the catalytic filter, whereby a higher efficiency of the engine is obtained. Thus, a performance gain and / or a reduced carbon dioxide emission can be obtained when the present invention is utilized.
By utilizing the present invention, the proportion of the nitrogen oxides NOX constituting nitrogen dioxide NO 2 can be actively controlled, which is made possible by an active control of the amount of nitrogen oxides NOX upstream of the first oxidation catalyst in the exhaust gas treatment system, which may for example comprise noble metal. This control of the NO2 / NOX ratio can, in addition to advantages in catalytic performance, such as higher NOX conversion, also provide the opportunity to reduce emissions of nitrogen dioxide NO3, which gives rise to a very toxic and strong-smelling emission. This can provide benefits in the event of a future introduction of a separate legal requirement for nitrogen dioxide NO2 through an opportunity to reduce emissions of nitrogen dioxide NO2.
BRIEF DESCRIPTION OF THE DRAWINGS The invention will be further elucidated below with reference to the accompanying drawings, in which like reference numerals are used for like parts, and in which: Figure 1 shows an exemplary vehicle which may include the present invention; Figures 2a and 2b show flow charts of the exhaust gas treatment process of the present invention. Figure 3 shows examples of exhaust gas treatment systems according to the present invention, Figure 4 shows a control unit in which a method according to the present invention can be implemented.
Description of Preferred Embodiments Figure 1 schematically shows an exemplary vehicle 100 including an exhaust gas treatment system 150, which may be an exhaust gas treatment system 150 according to an embodiment of the present invention. The driveline comprises a single-combustion engine 101, which in a conventional manner, via a shaft 102 emanating on the internal combustion engine 101, usually via a flywheel, is connected to a gearbox 103 via a clutch 106. The internal combustion engine 101 is controlled by the vehicle control system 115, which may be connected to the exhaust gas treatment system. 150 and / or its control unit 160. Likewise, the clutch 106 and the gearbox 103 can be controlled by the vehicle control system by means of one or more applicable control units (not shown). Of course, the driveline of the vehicle may also be of another type, such as of a type with a conventional automatic transmission, of a type with a hybrid driveline, etc.
A shaft 107 emanating from the gearbox 103 drives the drive wheels 113, 114 via an end shaft 108, such as e.g. a conventional differential, and drive shafts 104, 105 connected to said end shaft 108.
The vehicle 100 further includes an exhaust gas treatment system / exhaust purification system 150 pre-treatment / purification of exhaust emissions resulting from combustion in the combustion chamber of the internal combustion engine 101, which may be cylinders. The exhaust gas treatment system 150 can be controlled by the vehicle's control system via a control unit 160.
According to the present invention there is provided a process for treating an exhaust stream which results from a combustion in an internal combustion engine and comprises nitrogen oxides NOX. Nitrogen oxides include at least nitrogen monoxide NO and nitrogen dioxide NO2. The exhaust stream passes through an exhaust gas treatment system connected to the internal combustion engine.
This procedure can be illustrated by the flow chart in Figure 2a.
In a first step 210 of the process, a first oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen is carried out in the exhaust stream. This oxidation is carried out by a single oxidation catalyst arranged in the exhaust gas treatment system. In a second step 220 of the process, according to the present invention, a value (NO¿¿ / NOÄ¿) m% is determined for a ratio between a first amount of nitrogen dioxide NO¿¿ which leaves the first oxidation catalyst and reaches a catalytic filter SCRF and the first amount of nitrogen oxides NO & ¿which leaves the first oxidation catalyst and reaches the catalytic filter SCRF.
In a third step 230 of the method, an active control of at least one parameter related to the internal combustion engine is performed. This at least one parameter may, for example, be related to a combustion of the internal combustion engine. This active control is made according to the present invention based on the fixed value (NO¿¿ / NO & ¿) m¶ for the ratio and so that the active control affects a real value NO¿¿ / NO & ¿for the ratio.
In a fourth step 240 of the process, the first additive is supplied to the exhaust gas stream network by using a pre-dosing device arranged downstream of the first oxidation catalyst.
In a fifth step 250 of the process, a first reduction of the first amount of nitrogen oxides NO & ¿is carried out which flows out of the first oxidation catalyst and reaches a catalytic filter arranged downstream of the first dosing device. This reduction is carried out by a catalytic reaction with at least partial catalytic coating co-reduction. SCRF and through utilization of an additive.
By utilizing the present invention, the internal combustion engine can be controlled so that other of its emitted nitrogen oxides NOX if the determined value (NO¿¿ / NO & ¿) ¶¶ for the ratio is not optimal. Which value has been considered to be 10 l3 optimal depends on the purpose of the active control of the combustion parameters. Such an object may be to provide an effective sotoxidation in the catalytic filter. Another such object may be to provide an effective reduction of nitrogen oxides in the catalytic filter.
The supply of nitrogen dioxide NO¿¿ in the exhaust stream at the catalytic filter is important partly for the nitrogen dioxide-based deoxidation in the filter and partly for the reduction of nitrogen oxides NO & ¿. The exhaust gas treatment system of the present invention can therefore provide good sotoxidation in the catalytic filter due to the fact that the supply of nitrogen dioxide NO2 after the first oxidation catalyst can be reduced. In addition, the reaction rate of the first reduction can be affected by the ratio of nitrogen to nitrogen oxide NO2. the catalytic filter. A more efficient initial reduction in the catalytic filter may have been obtained due to the previous oxidation of nitrogen oxides NO¿ to nitrogen dioxides NO¿¿ in the first oxidation catalyst in combination with the activation control of the at least one parameter related to the internal combustion engine.
According to an embodiment of the present invention, the first supply is controlled by the first additive and / or the at least one motor-related parameter based on a distribution of the ratio between nitrogen dioxide and nitrogen oxides at / upstream of the catalytic filter NO¿¿ / NO & ¿and / or wide downstream device / reduction catalyst. NO & ¿, which may be in the form of established care (NO¿¿ / NO & ¿) m fi and / or (NO¿¿ / NO & ¿) m¶ for these conditions.The first supply of the first additive and / or the at least one motor-related the parameter may, for example, have been controlled based on a fixed value of 14 (NO¿¿ / NOÄ¿) m fi for the first ratio in such a way that rapid reduction can be used in the reduction in the catalytic filter, since it takes place as far as possible via reaction waves over both nitrogen oxide NO and nitrogen dioxide NO2.
According to an embodiment of the present invention, the active control of the at least one motor-related parameter is performed so that an increase of the first amount of nitrogen oxides NO & ¿is obtained if the determined value (NO¿¿ / NO & ¿) ¶¶ ratio is greater than or equal to an upper threshold value ( NO2_1 / NÛXñU thresholdnoia_highf (NÛzu / NOxñi) the 2 (NÛzu / NÛXñU thresholdhoiagigh -So the active control increases the first amount of nitrogen oxides NO & ¿if the set value (NO¿¿ / NO¿¿) is too large. increasing the first amount of nitrogen oxides NO¿¿ then decreases the value of the ratio.Increasing the first amount of nitrogen oxides NO & ¿may correspond to the fact that the first amount of nitrogen oxides NO & ¿which actually reaches the catalytic filter after the active control, i.e. after the effect of the ratio , is greater than the first amount of nitrogen oxides NO & ¿which is included in the fixed value (NO¿¿ / NO & ¿) ¶% for the ratio.The increase may also correspond to the actual first amount of nitrogen oxides NO & ¿after the active control have a higher concentration of nitrogen oxides in the exhaust gas than a concentration of the nitrogen oxides which corresponds to the determined value (NO¿¿ / NO & ¿) m¶ for the ratio.
The oxidation of nitric oxide NO to nitrogen dioxide NO2 over enoxidation catalyst DOC is chemically and catalytically affected because the catalytically oxidizing coating, for example comprising at least one noble metal such as platinum, is relatively constant under given conditions. Thus, the amount of nitrogen dioxide NO2 produced by an oxidation catalyst is DOC relative to the amount of nitrogen oxide NO fed to the oxidation catalyst DOC.
Such an increase in the initial amount of nitrogen oxides NO & ¿means that the true value of the NO¿¿ / NO & ¿ratio decreases, whereby the proportion of the total conversion of nitrogen oxides NOX which takes place via a rapid reaction wave can be increased. According to the internal combustion engine according to the present invention, the requirements for the catalyst volume are also reduced due to better utilization rate.
Thus, by this embodiment, the internal combustion engine is allowed to increase the first amount of nitrogen oxides NO & ¿which is emitted from the internal combustion engine and reaches the oxidation catalyst, and thus flows out the oxidation catalyst and reaches the catalytic filter, if the set value (NO¿¿ / NO & ¿) is too high. This increase in manganese nitrogen oxides NO & ¿reduces the value of the NO¿¿ / NO & ¿ratio, which means that a more efficient reduction can be obtained by means of the catalytic filter.
The upper threshold value (NO¿¿ / NO & ¿) ÜK% h @ Q¿bm, which if violated should give an active control of at least one motor-related parameter which causes an increase of the first amount of nitrogen oxides NOÄ¿, has according to an embodiment value which depends on a temperature above that catalytic filter and / or above a downstream reduction catalyst device. The upper threshold value (NO¿¿ / NO¿¿) ÜK% h @ Q¿¿m can, for example, have the value 45%, 50%, 60% or> 65%.
According to an embodiment of the present invention, the active control of the at least one motor-related parameter is performed so that the active control results in a reduction of the first amount of nitrogen oxides NO & ¿which reaches the catalytic filter about the determined value (NO¿¿ / NO & ¿) for the ratio is less than or equal to a wonder @ lVäId @ (NOgi / NO ;;) ume¶wu¿um, (NÛ¿; / NO ;;) mm 3 (NO¿¿ / NO¿¿) ÜHe¶wM¿hM. This decrease can be seen, for example, as the first amount of nitrogen oxides NO & ¿actually reaching the catalytic filter after the active control, i.e. after the influence of the ratio, is less than the initial amount of nitrogen oxides NO & ¿contained in the determined value (NO¿i / NO¿ ¿) M% for the ratio. The decrease can also be seen as the first amount of nitrogen oxides NO & ¿that actually reaches the catalytic filter after the active control has affected the ratio has a lower concentration of nitrogen oxides in the exhaust stream than a concentration of nitrogen oxides which corresponds to the set value (NO¿¿ / NO & ¿) m¶ for the ratio .
The lower threshold value (NO¿¿ / NO & ¿) Üme¶wM¿hW, which if it falls below, should give an active control that results in a reduction of the first amount of nitrogen oxides NO & ¿, has a single value which depends on a temperature above the catalytic filter and / or over a downstream device reducing catalyst device. The lower threshold value (NO¿¿ / NO¿¿) Üme¶wM¿hM can, for example, have a value corresponding to 50%, 45%, 30%, 20% or 10%.
As described above, according to the present invention, an active control 230 of at least one parameter related to the combustion in the engine is performed to provide an undesirable value for the ratio NO¿¿ / NO¿¿ between the first amount of nitrogen dioxide NO¿¿ and the first amount of nitrogen oxides NO & ¿which is the catalytic filter . This active control can be performed in a number of different ways according to different embodiments of the present invention. According to a couple of embodiments of the present invention, the active control 230 comprises a selection of at least one injection strategy for the internal combustion engine.
According to an embodiment of the present invention, the edge times for injection of fuel into the respective cylinder of the internal combustion engine are controlled in such a way that an increase or decrease of the first amount of nitrogen oxides NO & ¿which reaches the first oxidation catalyst, and thus also the catalytic filter, is achieved.
An increase in the first amount of nitrogen oxides NO & ¿can be achieved by bringing forward the timing of one or more of the injections. This increase in the initial amount of nitrogen oxides NOÄ¿ results in a decrease in the value of the NO¿¿ / NOÄ¿ ratio.
Correspondingly, the timing of injection fuel in each cylinder of the internal combustion engine can be controlled so that a reduction is made for the first amount of nitrogen oxides NO & ¿which reaches the reduction catalyst device. This reduction can be achieved by delaying the timing of one or more of the injections. This decrease in the first amount of nitrogen oxides NO & ¿increases the value of the NO¿¿ / NO & ¿ratio.
According to an embodiment of the present invention, the rabbit injection pressure for the injections of fuel and cylinder in the internal combustion engine is controlled so that an increase in the first amount of nitrogen oxides NO & ¿reaching the catalytic filter is achieved. This increase can be achieved by an increase in the injection pressure for one or more cylinders. This increase in the first amount of nitrogen oxides NO & ¿results in a decrease in the value of the NO¿¿ / NOÄ¿ ratio. Correspondingly, the injection pressure for the pre-injections of fuel into the respective cylinder of the internal combustion engine can be controlled so that a reduction of the first amount of nitrogen oxides NO & ¿which reach the catalytic filter is achieved. This reduction can be achieved by lowering the injection pressure of one or more cylinders. This decrease in the first amount of nitrogen oxides NO & ¿gives an increase in the value of the ratio NO¿¿ / NO & ¿.
According to an embodiment of the present invention, a single injection phase for an injection of fuel in the respective cylinder can be controlled so that an increase of the first amount of nitrogen oxides NO & ¿which reaches the reduction catalyst device is achieved. The increase may have been effected by controlling a single injection bevel so that it results in a relatively high pressure gradient. This increase in the first amount of nitrogen oxides NO & ¿results in a decrease in the value of the NO¿¿ / NO¿¿ ratio. In this document, co-injection phasing refers to how the injection changes over time, for example how the pressure for the injection changes over time. A measure related to the injection phase can be, for example, a time derivative of the cylinder pressure.
Correspondingly, an injection phase for single injection of fuel into the respective cylinder can be controlled so that a reduction of the first amount of nitrogen oxides NO & ¿which reached the catalytic filter is achieved. This reduction can be achieved by controlling the injection bevel so that it has a relatively small pressure gradient with respect to the cylinder pressure. This reduction of the first amount of nitrogen oxides NOÄ¿ gives an increase in the value of the ratio NO271 / Noxfl - 19 According to one embodiment of the present invention, the active control of the at least one engine-related parameter comprises a control of an Exchange Gas Recirculation (EGR) device. at an inlet with air to produce a gas mixture suitable for combustion together with fuel which is also supplied to the engine. In the engine cylinders, the combustion takes place, whereby the gas mixture is combusted. The combustion creates exhaust gases which leave the engine at one outlet. An exhaust gas recirculation can be arranged from the engine outlet to its inlet and in that case leads some of the exhaust gases back from the outlet to the inlet. As a result, the rabbit suction losses during the air suction are reduced and the amount of nitrogen oxides NOX out of the engine is adjusted. According to an embodiment of the present invention, the exhaust gas circulation is reduced, and in certain operating cases the exhaust gas circulation is switched off completely.
Thus, according to an embodiment of the present invention, an increase in the first amount of nitrogen oxides NO & ¿reaching the catalytic filter can be achieved by reducing a proportion of the exhaust gas stream recirculated by the pre-exhaust gas recirculation (EGR) device. This increase of the first manganese nitrous oxides NOÄ¿ results in a decrease in the value of the ratio No2fl / NOx / l °. Similarly, a decrease of the first manganese nitrogen oxides NO & ¿which reaches the catalytic filter can be achieved by increasing a proportion of the exhaust gas stream which is recirculated (EGR). This decrease in the initial amount of nitrogen oxides NO¿¿ increases the value of the NO¿¿ / NOÄ¿ ratio. 10 The determined value (NO¿¿ / NO & ¿) m% for the ratio between the first amount of nitrogen dioxide NO¿¿ and the first amount of nitrogen oxides NO & ¿which leaves, that is to say, flows out of, the first oxidation catalyst and reaches, that is, saga flows into , the catalytic filter may, for example, consist of a measured, predicted and / or modeled value ratio, where the feeding, predicting and / or modeling may take into account the current operating and / or driving case, characteristics of the road section on which the vehicle is located, characteristics of the internal combustion engine and / or characteristics of the industry used to drive the internal combustion engine. The feeding, predicting and / or modeling can also take into account how the vehicle is driven, such as the torque requested by a driver and / or a single-speed controller, as well as the driver's driving style. A predicted value dean, for example, is determined based on a representation of a wagon section in front of the vehicle, which can be based, for example, on positioning information, such as GPS information, and map data.
The determined value (NO¿¿ / NO & ¿) m% for the ratio between the first amount of nitrogen dioxide NO¿¿ and the first amount of nitrogen oxides NO & ¿which reach the catalytic filter can also be formed by a measured value, which is measured by using one or more NOX sensors and / or NO 2 sensors arranged in the exhaust gas treatment system.
In this document, the invention is often described as activation controls which result in increases or decreases in the amount of nitrogen oxides NOX which reach the first oxidation catalyst and thus also the catalytic filter. Those skilled in the art will appreciate that a method of processing an exhaust gas according to the present invention may additionally be implemented in a computer program, which when executed in a computer causes the computer to execute the method. The computer program is usually part of a computer program product 403, the computer program product comprises a suitable digital non-volatile / permanent / permanent / durable storage medium on which the computer program is stored. Named non-volatile / permanent / durable / durable computer readable media consists of a readable memory, such as, for example: ROM (Read-OnlyMemory), PROM (Programmable Read-Only Memory), EPROM (ErasablePROM), Flash memory, EEPROM (Electrically Erasable PROM ), single hard disk drive, etc.
Figure 4 schematically shows a control unit 400. The control unit 400 comprises a computing unit 401, which can be constituted by any suitable type of processor or microcomputer, e.g. a Digital SignalProcessor (DSP), or an Application Specific Integrated Circuit (ASIC). The computing unit 401 is connected to a memory unit 402 arranged in the control unit 400, which provides the computing unit 401 e.g. the stored program code and / or the stored data the computing unit 401 needs to be able to perform calculations. The calculation unit 401 is also arranged to store partial or final results of calculations in the memory unit 402.
Furthermore, the control unit 400 is provided with devices 411, 412, 413, 414 for receiving and transmitting input and output signals, respectively. These input and output signals may contain waveforms, pulses, or other attributes, which devices 411, 413 for receiving input signals may be detected as information and may be converted into signals which may be processed by the calculating unit 401. These signals are then provided to the calculating unit 401. The devices 412,414 for sanding of output signals are arranged to convert calculation results from the calculation unit 401 to output signals for transmission to other parts of the vehicle control system and / or the component (s) for which the signals are intended, for example to the first and / or second dosing devices.
Each of the connections to the devices for receiving and transmitting input and output signals, respectively, may be one or more of a cable; a data bus, such as a CAN bus (Controller Area Network bus), a MOST bus (Media OrientatedSystems Transport bus), or any other bus configuration; or by a wireless connection.
One skilled in the art will appreciate that the above-mentioned computer may be the debugging unit 401 and that the above-mentioned memory may be the memory unit 402.
In general, control systems in modern vehicles consist of a communication bus system consisting of one or more communication buses for interconnecting a number of electronic control units (ECUs), or controllers, and various components located on the vehicle. Such a control system can comprise a large number of control units, and the responsibility for a specific function can be divided into several other control units. Vehicles of the type shown thus often comprise considerably more control units than what is shown in Figures 13, 3 and 4, which is an option for those skilled in the art.
In the embodiment shown, the present invention is implemented in the control unit 400. However, the invention can also be implemented in whole or in part in one or more other control units already existing at the vehicle or in a control unit dedicated to the present invention.
In this document, control units are often described as being arranged to perform steps in the method according to the invention. This also includes that the units are adapted and / or arranged to perform these procedure steps. The control units can for instance correspond to groups of instructions, for example in the form of program code, which feeds in, and is used by, a processor when the respective control unit is active / used to perform the respective procedure steps.
According to one aspect of the present invention, there is provided an exhaust gas treatment system provided for treating single exhaust stream, which results from a combustion in a single combustion engine. The exhaust gas stream comprises nitrogen oxides NOX, in which at least nitrogen monoxide NO and nitrogen dioxide NO 2 are included. Figure 3 schematically shows a pair of different non-limiting examples of exhaust gas treatment system 350, in which the method according to the present invention can be used. The exhaust treatment system 350 shown in Figure 3 is a single exhaust line 302 connected to an internal combustion engine 301, which produces an exhaust stream 303 which, via the exhaust line 302, reaches the components of the exhaust treatment system 350.
The exhaust gas treatment system 350 of the present invention includes a first oxidation catalyst 311 disposed in the exhaust gas treatment system 350 to perform an oxidation 210 of compounds comprising one or more of nitrogen, carbon and hydrogen in the exhaust stream 303 from the internal combustion engine 301.
The exhaust gas treatment system 350 of the present invention also includes a first metering device 371 disposed downstream of the first oxidation catalyst 311 to perform a first supply 240 of a first additive in the exhaust stream 303 reaching a downstream metering device catalytic filter 320.
The catalytic filter 320 consists of a particle filter with at least partial catalytic coating with reduction properties. The catalytic filter 320 is arranged to capture and oxidize soot particles in the exhaust stream, and is arranged to carry out a pre-reduction 250 of the first amount of nitrogen oxides NO & ¿which reaches the catalytic filter 320. The catalytic reaction used in the filter has the first additive supplied to the exhaust stream. first dosing device 371.
The exhaust gas treatment system 350 of the present invention also includes a control unit 380 arranged to provide a above-described determination 220 of one-fourth (NO¿¿ / NO & ¿) m% for a ratio between a first nitrous oxide NO¿¿ and a first quantity of nitrogen oxides NO & ¿which call the first oxidation 311 and thus reaches the catalytic filter 320. The control unit 380 is also arranged to provide an active control 230 of at least one parameter related to an internal combustion engine 301 based on this determined value (NO¿¿ / NO & ¿) m¶ for the ratio. This active control 230 is arranged to influence the condition.
According to an embodiment of the present invention, the exhaust gas treatment system 350 further comprises a second metering device 372 disposed downstream of the catalytic filter 320 for performing a second supply of a second additive into the exhaust stream 303. According to this embodiment, the exhaust gas treatment system 350 includes a second reducing medium dispensing device 37. a second plurality of nitrogen oxides NO & ¿which reach the 10 reduction catalyst device 330. This second reduction utilizer may have any remaining first additive and / or the second additive. By utilizing this embodiment of the present invention, an improved radius oxidation in the catalytic filter can be obtained. More specifically, an improved passive nitrogen dioxide-based sotoxidation can be achieved because there are two possibilities for reducing nitrogen oxides in the exhaust gas treatment system, a first reduction in the catalytic filter and a second reduction in the reduction catalyst device. As a result, some of the nitrogen dioxide NO¿¿ which reaches the catalytic filter can be used to oxidize soot particles in the catalytic filter, instead of being consumed during the reduction with the catalytic coating in the filter.
In other words, the initial reduction of nitrogen oxides NO & ¿in the catalytic filter can be limited so that all nitrogen dioxide NO¿¿ in the exhaust stream is not consumed during that further reduction, whereby the rest of the nitrogen dioxide that has not been consumed can be used in the sotoxidation. This is possible because the exhaust gas treatment system, thanks to the fact that it also includes a reduction catalyst device downstream of the catalytic filter, can provide a total required / desired / desired reduction of nitrogen oxides NOX. Thereby it can thus be ensured that the required / desired NOx / waste / waste treatment system .
This embodiment also has an advantage in that two-dose devices are cooperatively used in combination pre-dosing of the reducing agent, for example urea, which relieves and facilitates mixing and possible evaporation of the reducing agent, since the injection of the reducing agent is distributed between two physically separated positions. This reduces the risk of the reducing agent locally cooling the exhaust gas treatment system, which can potentially form deposits at the positions where the reducing agent is injected, or downstream of these positions.
The control of the supply of the first additive according to one embodiment is performed based on one or more properties and / or operating conditions of the catalytic filter 320. The control of the supply of the first additive can also be controlled based on one or more properties and / or operating conditions of the reduction catalyst control device. The first additive can also be controlled based on a combination of properties and / or operating conditions of the catalytic filter and the reduction catalyst device.
Correspondingly, the control of the supply of the second additive can be performed based on one or more properties and / or operating conditions of the pre-reduction catalyst device 330. The control of the supply of the second additive can be carried out according to one embodiment based on one or more properties and / or operating conditions of the catalytic filter 320 the supply of the second additive can be diverted based on a combination of properties and / or operating conditions of the catalytic filter 320 and of the reduction catalyst device 330.
The above-mentioned properties of the catalytic filter 320 and / or of the reduction catalyst device 330 may be related to one or more of the catalytic properties of the catalytic filter 320 and / or of the reduction catalyst device 330, a catalyst type of the catalytic filter 320 and / or the pre-reduction catalyst device 330. , a temperature range in which the catalytic filter 320 and / or the reduction catalyst device 330 are active and the degree of depletion of ammonia for the catalytic filter 320 and / or for the reduction catalyst device 330.
According to an embodiment of the present invention, the exhaust gas treatment system 350 further comprises a second oxidation catalyst 312 disposed downstream of the catalytic filter 320 to perform a second oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen in said exhaust stream 303. The exhaust treatment system 350 further comprises a second dosing device. 312 for performing a second supply of a second additive in the exhaust stream 303. The exhaust gas treatment system further comprises having a reduction catalyst device 330 disposed downstream of the second metering device 372 to perform a second reduction of a second plurality of nitrogen oxides NO & ¿which the second reduction catalyst uses. or any residues of the first additive. The first oxidation catalyst DOC1311 and / or the second oxidation catalyst DOC2312 are at least partially coated with a catalytic oxidizing coating, wherein this oxidizing coating may comprise at least one noble metal, for example platinum. By utilizing this embodiment of the present invention, an improved sotoxidation in the catalytic filter can be obtained. More specifically, an improved passive nitrogen dioxide-based sotoxidation can be achieved because there are two possibilities for reducing nitrogen oxides in the exhaust gas treatment system, a first reduction in the catalytic filter and a second reduction in the reduction catalyst device. As a result, some of the nitrogen dioxide NO2 reaching the catalytic filter can be used to oxidize soot particles in the catalytic filter, instead of being consumed in the reduction with the catalytic coating in the filter. Thus, the first reduction of nitrogen oxides NOX in the catalytic filter can be limited so that not all nitrogen dioxide NO2 in the exhaust stream is consumed in the first reduction, whereby the rest of the nitrogen dioxide that is not consumed can be used in the sotoxidation. This is possible because the exhaust gas treatment system, thanks to the fact that it also includes a reduction catalyst device downstream of the catalytic filter, can provide an overall required reduction of nitrogen oxides NOX.
In addition, when this embodiment is utilized, an overall good reduction of nitrogen dioxide NOX can be provided to the medium rod gas treatment system 350, since the catalytic filter is preceded by an upstream first oxidation catalyst 3111 and the reduction catalyst device is preceded by an upstream second oxidation catalyst. the second reduction in the reduction catalyst device 330 is affected by the ratio between nitrogen monoxide NO and nitrogen dioxide NO2 in the exhaust stream. Thus, a more efficient first and second reduction in the catalytic filter 320 and the reduction catalyst device 330, respectively, can be obtained due to the previous oxidation of nitrogen oxide to nitrogen oxides.
In addition, the utilization of the two oxidizing steps in the first DOC1 311 and other DOC2 312 oxidation catalysts in the exhaust gas treatment system gives an increased proportion of nitrogen dioxide NO2 in the 10 29 exhaust stream when the exhaust stream reaches the catalytic filter SCRF and the reduction catalyst device, whereby a proportion of the total conversion reaction wave, that is to say via fast SCR (“solid SCR”) where the reduction takes place via reaction waves over both nitrogen monoxide NO and nitrogen dioxide NO2, okas.
This embodiment also has an advantage in that two-dose devices are cooperatively used in combination pre-dosing of the reducing / additive, for example urea, which relieves and facilitates mixing and possible evaporation of the additive, since the injection of the additive is distributed between two physically separated positions. This reduces the risk of the additive locally cooling down the exhaust gas treatment system, which could potentially form deposits at the positions where the additive is injected, or downstream of these positions.
According to one embodiment of the present invention, the reduction catalyst device 330 comprises a selective catalytic reduction catalyst (SCR).
The exhaust gas treatment system 350 may, according to one embodiment, have the DOC1-SCRF-SCR configuration according to the invention. That is, the exhaust gas treatment system 350 includes a pre-oxidation catalyst DOC1, downstream followed by a catalytic filter SCRF, that is, a particulate filter having at least partially catalytic coating with reduction properties, downstream followed by a selective catalytic reduction catalyst SCR. As mentioned above, the use of both the catalytic filter SCRF and the selectively catalytic reduction catalyst SCR in the exhaust gas treatment system 350 allows a slip catalyst SC to be omitted in the exhaust gas treatment system 350 for certain applications, which reduces the manufacturing cost of the vehicle. The first oxidation catalyst DOC1 can also be used to create heat in the exhaust gas treatment system according to the present invention, which can be used in regeneration of any exhaust gas treatment component, such as for example a reduction catalyst device or the catalytic filter in the exhaust gas treatment system. The two possibilities for reducing nitrogen oxides in the exhaust gas treatment system provided in the embodiment, the first reduction in the catalytic filter and the second reduction in the reduction catalyst device, make as mentioned above that part of the nitrogen dioxide NO2 reaching the catalytic filter can be utilized for catalytic use.
The exhaust gas treatment system 350 may, according to one embodiment, also have the configuration according to the invention DOC1-SCRF-DOC2-SCR. That is, the exhaust gas treatment system 350 comprises a first oxidation catalyst DOC1, downstream followed by a catalytic filter SCRF, i.e. a particle filter with at least partial reduction. of a second oxidation catalyst DOC2, downstream followed by a selective catalytic reduction catalyst SCR. As mentioned above, the use of both the catalytic filter SCRF and the selective catalytic reduction catalyst SCR in the exhaust gas treatment system 350 enables a slip catalyst SC to be cannulated in the exhaust gas treatment system 350 for certain applications, which reduces the manufacturing cost of the vehicle. The utilization of the two oxidizing steps in the first DOC1 and second DOC2 oxidation catalysts in the exhaust gas treatment system can give an increased proportion of nitrogen dioxide NO2 in the 10 3 exhaust gas stream when the exhaust gas stream reaches the catalytic filter SCRF and the reduction catalyst device, respectively. The first oxidation catalyst DOC1 can also be used to create heat in the exhaust gas treatment system of the present invention, which can be used in regenerating any exhaust gas treatment component, such as, for example, a single reduction catalyst device or the catalytic filter in the exhaust gas treatment system.
According to an embodiment of the present invention, the reduction catalyst device 330 comprises a selective catalytic reduction catalyst (SCR) downstream followed by a grinding catalyst (SC), wherein said grinding catalyst (SC) is arranged to oxidize a residue of additives and / or to assist the selective catalytic catalyst reduction catalyst (SCR). ) with a further reduction of nitrogen oxides NOX in the exhaust gas stream 303.
The exhaust gas treatment system 350 may, according to one embodiment, have the configuration according to the invention DOC1-SCRF-DOC2-SCR-SC. That is, the exhaust gas treatment system 350 comprises a first oxidation catalyst DOC1, downstream followed by a catalytic filter SCRF, i.e. a particle filter with partial reduction. followed by a second oxidation catalyst DOC2, downstream followed by a selective catalytic reduction catalyst SCR, downstream followed by enslip catalyst SC. This exhaust gas treatment system 350 enables emission levels for nitrogen oxides NOX close to zero, since the reduction catalyst SCR can be driven hard, for example by increasing the dosage of the second additive, the action being followed downstream of the grinding catalyst SC. The utilization of the grinding catalyst SC further improves the performance of the system, since further grinding can be taken care of by the grinding catalyst SC. According to an embodiment of the present invention, the slip catalyst SC is multifunctional, which means that it reduces nitrogen oxides NOX by utilizing residues of the additive and also the oxidizer residues of the additive. In addition, the use of the two oxidizing steps in the first DOC1 and second DOC2 oxidation catalysts in the exhaust gas treatment system provides an ocad share of nitrogen dioxide NO2 in the exhaust stream when the exhaust stream reaches the catalytic filter SCRF and the reduction catalyst device, whereby the proportion of dentave The SCR ("solid SCR") tremor reduction takes place via reaction scales over both nitrogen monoxide NO and nitrogen dioxide NO2, okas. The first oxidation catalyst DOC1 can also be used to create heat in the exhaust gas treatment system of the present invention, which can be used in regenerating any exhaust gas treatment component, such as for example by a reduction catalyst device or by the filter SCRF in the exhaust gas treatment system. The two possibilities for the reduction of nitrogen oxides in the exhaust gas treatment system provided by the embodiment, the first reduction in the catalytic filter and the second reduction in the reduction catalyst device, allow some of the nitrogen dioxide NO2 + which reaches the catalytic filter to be used in the oxidant. during the reduction with the catalytic coating in the filter. Thus, the residual reduction of nitrogen oxides NO & ¿in the catalytic filter can be limited so that not all the nitrogen dioxide NO2 in the exhaust stream is consumed in the first reduction, whereby the rest of the nitrogen dioxide which has not been consumed can be utilized in the wide oxidation. This is possible because the exhaust gas treatment system, thanks to the fact that it also includes a reduction catalyst device downstream of that catalytic filter, can provide an overall required reduction of nitrogen oxides NOX. By utilizing the present invention, therefore, an improved passive nitrogen dioxide-based sotoxidation in the catalytic filter can be obtained.
The exhaust gas treatment system 350 may, according to one embodiment, have the inventive configuration DOC1-SCRF-SCR-SC. That is, the exhaust gas treatment system 350 includes a first oxidation catalyst DOC1, downstream of a single catalytic filter SCRF, that is, a particulate filter having at least partial catalytic coating with reduction properties, downstream followed by a selective catalytic reduction catalyst folate SCRF, a downstream catalyst SCRF. This exhaust gas treatment system 350 allows emission levels for nitrogen oxides NOX near zero, since the reduction catalyst SCR can be driven hard, for example by increasing the dosage of the second additive, the dew is followed downstream of the grinding catalyst SC. The utilization of the abrasive catalyst SC further improves the performance of the system, since additional abrasive can be taken care of the abrasive catalyst SC. According to one embodiment of the present invention, the slip catalyst SC is multifunctional, which means that it reduces nitrogen oxides NOX by utilizing residues of the additive and also the oxidizer residues of the additive. In addition, the utilization of the two oxidizing steps of the first DOC1 and second DOC2 oxidation catalysts in the exhaust gas treatment system provides an ocad share of nitrogen dioxide NO2 in the exhaust stream as the exhaust stream reaches the catalytic filter SCRF and the reduction catalyst device, respectively. The primary oxidation catalyst DOC1 can also be used to create heat in the exhaust gas treatment system of the present invention, which can be used in regenerating any exhaust gas treatment component, such as, for example, a single reduction catalyst device or the filter in the exhaust gas treatment system. The two possibilities of reducing nitrogen oxides in the exhaust gas treatment system provided by the embodiment, the first reduction in that catalytic filter and the second reduction in the reduction catalyst device, allow some of the nitrogen dioxide NO 2 reaching the catalytic filter to be used to oxidize the soot particles. This configuration is compact in relation to its performance / utilization rate.
According to an embodiment of the invention, a first and / or a second hydrolysis catalyst, which can be constituted by substantially any suitable hydrolysis coating, and / or at least one mixer can be arranged in connection with the first 371 and the second 372 dosing device, respectively. The first and / or second hydrolysis catalyst and / or the at least one mixer is then used to increase the rate of degradation of urea to ammonia and / or to mix the additive with the emissions and / or to evaporate the additive.
The exhaust gas treatment system 350 may also be provided with one or more sensors, such as one or more NOX, NO 2 and / or temperature sensors 361, 362, 363, 364, 365 arranged at the inlet to the first 311 and / or second 312 oxidation catalyst, for example at the inlet and / or the outlet to the catalytic filter 320, at the inlet to the reduction catalyst device 330 and / or to the outlet from the reduction catalyst device 330, for determining nitrogen oxides and / or temperatures in the exhaust gas treatment system.
According to one embodiment, the exhaust gas treatment system 350 may comprise at least one external injector which supplies the first 311 and / or the second 312 oxidation catalyst with the hydrocarbon HC.
The engine can also be seen as an injector which supplies the first 311 and / or the second 312 oxidation catalyst with the hydrocarbons HC, where the hydrocarbons HC can be used to generate heat.
The exhaust gas treatment system 350 according to one embodiment also comprises the above-mentioned control unit 380 arranged to provide / perform a determination 220 of a value (NO¿¿ / NO & ¿) m% for a ratio between the first amount of nitrogen dioxide NO¿¿ which reaches the catalytic filter 320 and the first amount nitrogen oxides NO & ¿which leaves the primary oxidation catalyst 311 and thus also reaches the catalytic filter 320 as described above. The control unit 380 is further arranged to perform an active control 230 of at least one parameter related to the internal combustion engine 301, such as for example related to an internal combustion pre-combustion engine, based on this determined value (NO¿¿ / NO¿¿) m% for the ratio. This active control 230 is implemented so that the value of the ratio NO¿¿ / NO & ¿others. The control unit 380 may be arranged to base the control on signals from one or more sensors in the exhaust gas treatment system, among others on the one or more of the NOX, NO2 and / or temperature sensors 361, 362, 363, 364,365.
As a non-limiting example, the control may have been carried out so that the dosage of the first additive very much corresponds to a NOX conversion exceeding the value for 2 times the ratio between the proportion of nitrogen dioxide NO 2 and the proportion of nitrogen oxides 10 36 NOX, i.e. the dosage of the first additive corresponds to a NOX -conversion less than (NO2 / NOX) * 2. If, for example, NO 2 / NOX = 30%, then the dosage of that forstat additive can be controlled to correspond to a NOX conversion less than 60% (2 * 30 ° = 60%), for example a NOX conversion equal to about 50%, which would guarantee that the reaction rate over the catalytic filter 320 is fast and that 5% nitrogen dioxide NO2 is present for NO2-based sotoxidation in the catalytic filter 320.
According to an embodiment of the present invention, the control unit 380 is arranged to also determine a second value (NO¿¿ / NO & ¿) m% for a ratio between the second amount of nitrogen dioxide NO¿¿ and the second amount of nitrogen oxides NO & ¿as the reduction catalyst device 330. The control unit 380 is also arranged to perform the active control 230 of the at least one motor-related parameter based on both the above-determined fixed value (NO¿¿ / NO & ¿) m% and on the fixed second value (NO¿¿ / NO & ¿) m% on the ratio. This can provide a more robust control, for example in the event of an operation it is difficult to reliably determine that value (NO¿¿ / NOÄ¿) ¶%. This embodiment is illustrated in Figure 2b, in which the process steps are performed in at least partially different order from that shown in Figure 2a.
In the process shown in Figure 2b, in a first step the first oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen in the exhaust stream is carried out. This oxidation provided a first oxidation catalyst arranged in the exhaust gas treatment system.
In a second step 220b of the process, a value (NO¿¿ / NO & ¿) m% is determined for a ratio between a first amount of nitrogen dioxide NO¿¿ which leaves the first 10 37 oxidation ketälysäter and when a ketälytic filter SCRF and the first amount of nitrogen oxides NO & ¿ which leaves the first oxidation kätälysätor and when the kätälytiskä filter SCRF.
In a third step 230b of the front end, the exhaust gas drum is first supplied with additives by utilizing a pre-dosing device located just below the first oxidation boiler.
In a fourth step 240b of the foregoing, a preamble reduction is performed on the first amount of nitrogen oxides NO & ¿which flows out of the first oxidation kettle lysator and when a ketälytic filter is still downstream of the preamble dosing device. This reduction is carried out by questionnaire reaction with an at least partial chain analyte coating with reduction properties in the SCRF of the chain filter and by utilizing the first additive.
In a fifth step 250b of the foregoing, a value (NO¿¿ / NO & ¿) m% is set for a ratio between a different amount of nitrogen dioxide NO¿¿ which, when downstream of the kätälytiskäfilter, is the reduction kätälysätorrän 330 and the other amount of nitrous oxide is NO & iode.
In a sixth step 260b of the front end, an active control is performed on at least one pearmeter relay wheel for the internal combustion engine. This at least one pearmeter may, for example, be a relay wheel for a combustion engine for the internal combustion engine. According to the present invention, this asset control is based on fixed values (NO¿¿ / NO & ¿) m% and / or other (NO¿¿ / NO & ¿) current values for the relative and is performed in such a way that the active control affects the corresponding actual values for the relative. As described above, according to the present invention, an active control 230 of at least one parameter related to the combustion in the engine 301 is performed to provide a desired value for the ratio between the first set of nitrogen dioxide NO2 and the first set of nitrogen oxides NO & which reach the catalytic filter and / or corresponding amounts. NO¿¿ / NO & ¿which reaches the reduction catalyst device. This asset control can be performed in a number of different ways according to different embodiments of the present invention.
The active control of the at least one parameter related to the combustion in the engine 301 may according to one embodiment of the present invention comprise a choice of at least one injection strategy for the internal combustion engine 301. In Figure 3 the control unit 380 is schematically drawn as connected to the engine 301. By this connection is meant that the control unit 380 to be able to control the injection of fuel into the cylinders of the internal combustion engine, either directly or via an engine control unit 115 (figure 1).
According to one embodiment of the present invention, a timing of an injection of fuel into the respective cylinder of the internal combustion engine 301 may be controlled by the control unit 380 to occur earlier, an increase of the first amount of nitrogen oxides NO & ¿reaching the catalytic filter 320 being achieved by earlier timing of the pre-injection. Correspondingly, a reduction of the first amount of nitrogen oxides NO & ¿which reaches the catalytic filter 320 can be achieved by delaying the time of injection.
According to an embodiment of the present invention, as described above, the injection pressure for the injections of fuel into the respective cylinder of the internal combustion engine can be controlled by the control unit 380 so that an increase of the injection pressure is achieved for one or more cylinders, an increase of the first amount of nitrogen oxides NO the catalytic filter 320 is provided. Correspondingly, the rabbit injection pressure for the injections of fuel and respective cylinder into the internal combustion engine 301 is controlled so that a reduction of the first amount of nitrogen oxides NO & ¿which reaches the filter 320 is achieved.
According to an embodiment of the present invention, as described above, an injection phase for an injection of fuel in each cylinder can be controlled by the control unit 380 so that a relatively large pressure gradient is obtained, thereby increasing the first amount of nitrogen oxides NO & ¿which reaches the catalytic filter 320. Correspondingly, the rabbit injection bevel is controlled so that a relatively small cylinder pressure gradient is obtained, whereby a reduction of the first amount of nitrogen oxides NOA + which reaches the filter 320 is achieved.
As described above, according to one embodiment of the present invention, the active control of the at least one combustion-related parameter may include that the control unit 380 controls an Exchange Gas Recirculation (EGR) device 304. This is illustrated schematically in Figure 3 by a coupling between the control unit 380 and the exhaust gas recirculation device. that the control unit 380 can either directly or via, for example, an engine control unit 115 (figure 1) control the proportion of the exhaust gas stream 303 which is recirculated from the engine outlet 305 to its inlet 306. For example, the control unit 380 may be arranged to control a throttle or the like in the EGR return 304. of the exhaust gases recirculated to the inlet 306.
According to one embodiment of the present invention, the control unit 380 may be arranged to reduce a proportion of the exhaust gas stream recirculated by the pre-exhaust gas recirculation (EGR) device, thereby increasing the amount of nitrogen oxides NO2 which reach the catalytic filter 320. According to one embodiment, the recirculation can be reduced to zero. Correspondingly, an increase in the proportion of the exhaust gas stream which is recirculated by the exhaust gas recirculation (EGR) device can reduce the initial amount of nitrogen oxides NO & ¿which reaches the filter 320.
According to an embodiment of the present invention, the first and / or the second additive comprises ammonia NH 3 or urea, or a composition from which ammonia is congenerated / formed / released. This additive may, for example, consist of AdBlue. The first and second additives may be of the same kind, or may be of different kinds.
According to an embodiment of the present invention, the exhaust gas treatment system 350 comprises a system 370 for supplying additives, which comprises at least one pump 373 arranged to supply the first 371 and the second 372 dosing device in the exhaust gas treatment system 350 with additives, i.e. with for example ammonia or UIGÖ.
An example of such a supply additive system 370 is shown schematically in Figure 3, where the system includes the first metering device 371 and the second metering device 372, which are arranged upstream of the catalytic filter SCRF 320 and the upstream reduction catalyst device 330, respectively. The first 371 and other 372 dispensers. of 41 metering nozzles dispensing additives to, and mixing these additives with, the exhaust stream 303, supply additives of the at least one pump 373 via additive lines 375. The at least one pump 373 receives the additive from one or more tanks 376 additives via one or more lines 377 the intermediate tank (s) 376 and the at least one pump 373. It will be appreciated that the additive may be in liquid and / or gaseous form. When the additive is in liquid form, the pump 373 is a liquid pump and the one or more tanks 376 are liquid containers. When the additive is in gaseous form, the pump 373 is a gas pump and the one or more tanks 376 are gas containers. If both gaseous and liquid additives are used, several tanks and pumps are used, where at least one tank and one pump are provided to provide liquid additives and at least one tank and one pump. are designed to provide gaseous additive.
According to an embodiment of the invention, the at least one pump 373 comprises a common pump which feeds both the first 371 and the second 372 dosing device with the first and second additive respectively. According to another embodiment of the invention, the at least one pump comprises a first and a second pump, which feed the first 371 and the second 372 dosing device, respectively, with the first and second additive, respectively. The specific function of the additive system 370 is the choice described in the prior art, and the exact procedure for injecting the additive is therefore not described in more detail. In general, however, the temperature at the injection point / SCR catalyst should be above a subsurface temperature to avoid precipitation and the formation of undesirable by-products, such as ammonium nitrate NH @ Mh. An example of a value for such a lower 42 spruce value temperature may be about 180 ° C. According to one embodiment of the invention, the additive pre-supply system 370 comprises a metering control unit 374 arranged to control the at least one pump 373 so that the additive is supplied with the exhaust gas stream. The metering control unit 374 comprises, in one embodiment, a first pump control unit 378 arranged to control the at least one pump 373, such that a first metering of the first additive is supplied to the exhaust gas stream 303 via the first metering device 371. The dosing control unit 374 also comprises a second pump control unit 379 arranged to control the at least one pump 373 in such a way that a second dosing of the second additive is supplied to the exhaust gas stream 303 via the second dosing device 372.
The first and second additives are usually the same type of additive, for example urea. However, according to one embodiment of the present invention, the first additive and the second additive may be of different types, for example urea and ammonia, causing the dosing upstream of each of the catalytic filter SCRF 320 and the reduction catalyst device 330, and thus the function of each of the catalytic the filter SCRF 320 and the reduction catalyst device 330 can be optimized also with respect to the type of additive. If different types of additives are used, the tank 376 comprises several sub-tanks, which contain the different respective types of additives. One or more pumps 373 can be used to supply different types of additives to the pre-dosing device 371 and the second dosing device 372. As mentioned above, the one or more tanks and the one or more pumps are adapted to the condition of the additive 43, i.e. whether the additive is gaseous or liquid.
The one or more pumps 373 are thus controlled by a dosing control unit 374, which generates control signals for controlling the supply of additives so that the desired quantity is injected into the exhaust gas stream 303 by means of the first 371 and second 372 dosing device upstream of the first331 and second 332 devices, respectively. In more detail, the first pump control unit 378 is arranged to control either a single pump, or a pump dedicated to the first metering device 371, whereby the first metering is controlled to supply the exhaust gas stream 303 via the pre-metering device 371. The second pump control unit 379 is arranged to control either a common pump, or a for the second metering device 372 dedicated pump, whereby the second metering device is controlled to be supplied to the exhaust gas stream 303 via the second metering device 372.
The exhaust gas treatment system 350 in which the present invention is implemented can have a wide variety of configurations. As the name implies, the exhaust gas treatment system may have substantially any appearance, as long as it includes at least one first oxidation catalyst 311 followed by a catalytic filter SCRF 320, followed by a reduction catalyst device 330, and where the combustion engine 301 may be controlled by a control unit 380 to second the first NO & ¿emitted from the engine.
In this document, selective catalytic reduction catalyst SCR refers to a traditional selective catalytic reduction (SCR) catalyst. SCR catalysts use an additive, often ammonia NH3, or a composition from which ammonia can be generated / formed, which is used for the reduction of the nitrogen oxides NOX in the exhaust gases. The additive is injected into the exhaust gas stream from the internal combustion engine upstream of the catalyst as described above. The additive supplied to the catalyst is adsorbed (stored) in the catalyst, in the form of ammonia NH3, whereby a redox reaction can take place between nitrogen oxides NOX in the exhaust gas and by addition to ammonia.
In this document, by means of grinding catalyst SC is meant a catalyst which is arranged to oxidize additives and / or to assist a selective catalytic reduction catalyst SCR with a reduction of nitrogen oxides NOX in the exhaust gas stream.
The system according to the present invention can be arranged to perform all the process embodiments described above, and in the claims, the system for each embodiment receiving the above-described advantages for each embodiment.
Those skilled in the art will also appreciate that the above system may be modified according to various embodiments of the method of the invention. In addition, the invention relates to a motor vehicle 100, for example a truck or a bus, comprising at least one system for treating an exhaust stream.
The present invention is not limited to the embodiments of the invention described above, but relates to and includes all embodiments within the scope of the appended independent claims.

权利要求:
Claims (33)
[1]
A process for treating an exhaust stream (303), which results from a combustion in an internal combustion engine (301), passes through an exhaust gas treatment system (350), and comprises nitrogen oxides NOX, wherein said nitrogen oxides NOX include nitrogen monoxide NO and nitrogen dioxide NO 2; characterized by a first oxidation (210) of compounds comprising one or more of nitrogen, carbon and cotton in said exhaust stream (303), wherein said first oxidation (210) is carried out by a first oxidation catalyst (311) arranged in said exhaust gas treatment system (350); a determination (220) of a value (NO¿¿ / NO & ¿) m¶ for a ratio between a first amount of nitrogen dioxide NO¿¿ and a first amount of nitrogen oxides NO & ¿which leave said first oxidation catalyst (311); an active control (230) of at least one parameter related to said internal combustion engine (301) based on name fixed values (NO¿¿ / NO & ¿) m% for said ratio, said active control (230) influencing said ratio; - a first supply (240) of a first additive in said exhaust stream (303) by utilizing a first metering device (371) arranged downstream of said first oxidation catalyst (311); a first reduction (250) of said first amount of nitrogen oxides NO & ¿by a catalytic reaction in a catalytic filter (320) arranged downstream of said first dosing device (371), said catalytic filter (320) consisting of a particle filter with an at least partially catalytic coating with reduction , which is arranged for capturing and oxidizing soot particles, and for carrying out said first reduction of said first amount of nitrogen oxides NO & ¿, and in which said catalytic reaction uses said first additive.
[2]
The method of claim 1, wherein said activation control (230) of at least one parameter related said internal combustion engine (301) is performed so that said control results in an increase of said first set of nitrogen oxides NO & ¿if said fixed value (NO¿¿ / NO & ¿) m¶ for name ratios is greater than or equal to an upper threshold value (NO2_1 / NÛXñU thresholdhoia_nighf (NÛ2_1 / NÛXñU the 2 (NÛzu / NÛXñU thresholdhoiagigh -
[3]
A method according to claim 2, wherein said increasing of said first amount of nitrogen oxides NO & ¿meant that the first amount of nitrogen oxides NO & ¿after said influence of name ratio is greater than said first amount of nitrogen oxides NO & ¿which is included in said fixed value (NO¿¿ / NO & ¿ ) m¶ for the said relationship.
[4]
A method according to any one of claims 2-3, wherein said increasing of said first amount of nitrogen oxides NO¿¿ means said first amount of nitrogen oxides NO & ¿after said influence of said ratio has a higher concentration of nitrogen oxides in said exhaust stream than a concentration of nitrogen oxides corresponding to said fixed value. (NO¿¿ / NOÄ¿) ¶¶ for the said relationship.
[5]
A method according to any one of claims 2-4, wherein said upper threshold value (NO¿¿ / NO & ¿) ÜK% hMQ¿rm has a value corresponding to one in the group of: - 45%; 50%; 60%; and -> 65%. 47
[6]
A method according to any one of claims 2-5, wherein said upper threshold value (NO¿¿ / NO & ¿) Üm% hMQ¿¿m has a value which depends on a temperature above said catalytic filter (320) and / or above a downstream said catalytic filter (320). catalytic filter reduction catalyst device (330).
[7]
The method of claim 1, wherein said activating control of said at least one single combustion parameter for said internal combustion engine (301) is performed so that said control results in a reduction of said predominant nitrogen oxides NO & ¿if said fixed value (NO¿¿ / NO¿¿ ) ¶% for the said ratio is less than or equal to the lower threshold value (NO¿¿ / NO & ¿) Üme¶wM¿hM, (NO¿¿ / NO & ¿) m¶ S (NO2_1 / NOXñU thresholdhoiauow -
[8]
A method according to claim 7, wherein the name reduction of said first amount of nitrogen oxides NO & ¿meant that said first amount of nitrogen oxides NO & ¿after said influence said ratio is less than said first amount of nitrogen oxides NO & ¿which is included in said fixed value (NO¿¿ / NOÄ¿). ¶¶ for the said relationship.
[9]
A method according to any one of claims 7-8, wherein said reducing of said first amount of nitrogen oxides NO 'means that said first amount of nitrogen oxides NO & ¿after name influence of said ratio has a lower concentration of nitrogen oxides in said exhaust stream than a concentration of nitrogen oxides corresponding to said fixed NO¿¿ / NO & ¿) ¶¶ for the said relationship.
[10]
A method according to any one of claims 7-9, wherein said lower threshold value (NO¿¿ / NO & ¿) Üme¶wM¿hM has a value corresponding to one in the group of: - 50%; - 45%; lO 48
[11]
11. ll. A method according to any one of claims 7-10, wherein said lower threshold value (NO¿¿ / NO & ¿) Üme¶wM¿hM has a value which depends on a temperature above said catalytic filter (320) and / or over a reduction catalyst device arranged downstream of said catalytic filter. (330).
[12]
12. l2. A method according to any one of claims 1 to 11, wherein said active control of said at least one parameter comprises a selection of at least one injection strategy for said internal combustion engine (30l).
[13]
13. l3. A method according to claim 12, wherein said at least one injection strategy comprises a control of time d for an injection of fuel into the respective cylinder in said internal combustion engine (301).
[14]
14. l4. A method according to claim 13, wherein an increase in said first amount of nitrogen oxides NO € ™ is accomplished by an advance of said time d for said injection.
[15]
15. l5. A method according to claim 12, wherein a reduction of said first amount of nitrogen oxides NO & ¿is achieved by delaying said time d for said injection.
[16]
16. l6. A method according to any one of claims 12-25, wherein said at least injection strategy comprises a control of an injection pressure for an injection of fuel into the respective cylinder of said internal combustion engine (301).
[17]
17. l7. A method according to claim 16, wherein an increase in said first amount of nitrogen oxides NO & ¿is achieved by an increase in said injection pressure. 49
[18]
The method of claim 16, wherein a reduction of said first amount of nitrogen oxides NO € ™ is accomplished by lowering said injection pressure.
[19]
A method according to any one of claims 12-18, wherein said at least injection strategy comprises a control of an injection bevel for an injection of fuel into the respective cylinder of said internal combustion engine (301).
[20]
A method according to claim 19, wherein an increase in said first amount of nitrogen oxides NO & ¿is produced by controlling an injection phase which produces a relatively large pressure gradient.
[21]
A method according to claim 19, wherein a reduction of said first amount of nitrogen oxides NO €
[22]
A method according to any one of claims 1-20, wherein said active control of said at least one parameter comprises a control of an exhaust gas recirculation device (EGR; 304).
[23]
The method of claim 22, wherein an increase in said first amount of nitrogen oxides NO & ¿is achieved by decreasing a portion of said exhaust gas stream which is recirculated by said exhaust gas recirculation device (EGR; 304).
[24]
The method of claim 22, wherein a reduction of said first amount of nitrogen oxides NO & ¿is accomplished by increasing a portion of said exhaust gas stream which is recirculated through said exhaust gas recirculation device (EGR; 304).
[25]
A method according to any one of claims 1-24, wherein said determined value (NO¿¿ / NO & ¿) m¶ for said ratio l0 consists of one in the group of: - a predicted value; - a modeled value; and - a measured value.
[26]
A method according to any one of claims 1 to 25, further comprising: - a second supply of a second additive in said exhaust gas stream (303) by utilizing a second dosing device (372) arranged downstream of said catalytic filter (320); and - a second reduction of a second plurality of nitrogen oxides NO & ¿wherein a reduction catalyst device (330) is arranged downstream of said second dosing device (372), said second reduction utilizing said first and / or second additives.
[27]
A process according to any one of claims 1 to 25, further comprising: - a second oxidation of compounds comprising one or more of nitrogen, carbon and cotton in said exhaust stream (303), wherein said second oxidation is performed by a second oxidation catalyst (312) arranged downstream of said catalytic filters (320); - a second supply of a second additive in said exhaust gas stream (303) by utilizing a down-dose device (372) arranged downstream of said second oxidation catalyst (312); and - a second reduction of a second plurality of nitrogen oxides NO & ¿wherein a reduction catalyst device (330) is arranged downstream of said second dosing device (372), said second reduction utilizing said first and / or second additives.
[28]
A computer program comprising program code, said program code being executed in a computer causing said computer to perform the method of any of claims 1-27.
[29]
A computer program product comprising a computer readable medium and a computer program according to claim 28, wherein said computer program is included in said computer readable medium.
[30]
An exhaust gas treatment system (350) arranged for treating an exhaust gas stream (303), which results from a combustion in an internal combustion engine (301) and comprising nitrogen oxides NOWs said nitrogen oxides NOX comprises nitrogen monoxide NO and nitrogen dioxide NO 2; characterized by - a first oxidation catalyst (311) arranged in said exhaust gas treatment system (350) for an oxidation (210) compounds comprising one or more of nitrogen, carbon and hydrogen in said exhaust stream (303); a control unit (380) arranged to provide: - a determination (220) of a value (NO¿¿ / NO & ¿) m% for a ratio between a first quantity of nitrogen dioxide NO¿¿ and a first quantity of nitrogen oxides NO & ¿which leave the first oxidation catalyst (311); and - an active control (230) of at least one parameter related to an internal combustion engine (301) based on name fixed values (NO¿¿ / NO & ¿) m% for said ratio, said active control (230) influencing said ratio; - a first metering device (371) disposed downstream of said first oxidation catalyst (311) for performing a first feed (240) of a first additive in said exhaust gas stream (303); a catalytic filter (320) arranged downstream of the first dosing device (371), wherein said catalytic filter (320) is constituted by a particulate filter having an at least partially catalytic coating with reducing properties, which is arranged for capturing and oxidizing soot particles, and for performing a reduction (250) of said first amount of nitrogen oxides NO & ¿, and where a catalytic reaction said first reduction (250) utilizes said first additive.
[31]
The exhaust gas treatment system (350) of claim 30, further comprising: - a second metering device (372) disposed downstream of the named catalytic filter (320) for performing a second supply of second additives in said exhaust stream (303); and - a reduction catalyst device (330) arranged downstream of said second dosing device (372) for performing a second reduction of a second plurality of nitrogen oxides NO, which when said reduction catalyst catalyst device (330), said second reduction utilizing said first and / or second additives.
[32]
The exhaust gas treatment system (350) of claim 30, further comprising: - a second oxidation catalyst (312) disposed downstream of said catalytic filter (320) to perform a second oxidation of compounds comprising one or more of nitrogen, carbon and cotton in said exhaust stream (303) ; a second metering device (372) arranged downstream of said second oxidation catalyst (312) for performing a second supply of a second additive in said exhaust stream (303); and - a reduction catalyst device (330) arranged downstream of said second metering device (372) for performing a a second plurality of nitrogen oxides NO, which when said reduction catalyst device (330), said second reduction utilizing said first and / or second additives.
[33]
An exhaust gas treatment system (350) according to any one of claims 30-32, wherein said reduction catalyst device (330) comprises someone in the group of: - a selective catalytic reduction catalyst (SCR); a selective catalytic reduction catalyst (SCR) downstream of a grinding catalyst (SC), said grinding catalyst (SC) being arranged to oxidize a residue of additive and / or to assist said selective catalytic reduction catalyst (SCR) with a further reduction of nitrogen oxides NOX in said exhaust stream (303); and - a grinding catalyst (SC), which is arranged primarily for the reduction of nitrogen oxides NOX and secondarily for the oxidation of additives in said exhaust gas stream (303).

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同族专利:

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公开号 | 公开日

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EP3341597B1|2021-05-12|

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EP3341597A4|2019-01-23|

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US20180223759A1|2018-08-09|

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BR112018002005A2|2018-09-18|

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US10724460B2|2020-07-28|

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EP3341597A1|2018-07-04|

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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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SE1551107A|SE539130C2|2015-08-27|2015-08-27|Process and exhaust treatment system for treating an exhaust stream|SE1551107A| SE539130C2|2015-08-27|2015-08-27|Process and exhaust treatment system for treating an exhaust stream|

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US15/750,162| US10724460B2|2015-08-27|2016-08-25|Method and system for treatment of an exhaust gas stream|

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KR1020207011070A| KR20200043520A|2015-08-27|2016-08-25|Method and system for treatment of an exhaust gas stream|

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BR112018002005A| BR112018002005A2|2015-08-27|2016-08-25|method for treating an exhaust gas stream|

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EP16839706.5A| EP3341597B1|2015-08-27|2016-08-25|Method and system for treatment of an exhaust gas stream|

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PCT/SE2016/050795| WO2017034464A1|2015-08-27|2016-08-25|Method and system for treatment of an exhaust gas stream|

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KR1020187007502A| KR20180041194A|2015-08-27|2016-08-25|Systems and methods for treating exhaust gas streams|